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Experimental and modeling studies on installation of arc sprayed Zn anodes for protection of reinforced

Xianming SHI

《结构与土木工程前沿（英文）》 2016年 第10卷 第1期   页码 1-11 doi: 10.1007/s11709-016-0312-7

摘要： Arc sprayed zinc (Zn) anode on concrete surfaces has been an emerging technology for protecting reinforced concrete structures from rebar corrosion in coastal environments. Many cathodic protection (CP) systems with arc sprayed Zn anodes will reach or exceed their design life in the near future and thus may function improperly or insufficiently, making it necessary to replace the aged anodes. However, prior to this study, little was known about the most effective profile for the concrete surface, for either new concrete or old concrete with existing Zn anodes removed. This work develops criteria to properly prepare the concrete surface before the application of new Zn anode. Experimental studies were conducted both in the laboratory and for a field structure in Oregon. Artificial neural network was used to achieve better understanding of the complex cause-and-effect relationships inherent in the Zn-mortar or Zn–concrete systems and was successful in finding meaningful, logical results from the bond strength data. The goal is to achieve strong initial bond strength of new Zn to concrete, which is essential for long-term performance of the CP system. The results from this case study suggest that it is necessary to adjust the anode removal and surface sandblasting based on the electrochemical age of the existing concrete. In all cases of sandblasting, minimize the exposure of large aggregates (e.g., those bigger than 19 mm in diameter).

关键词： arc sprayed Zn     anode replacement     reinforced concrete     bridge preservation     neural networks     surface profile    

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Stress field near circular-arc interface crack tip based on electric saturation concept

Longchao DAI, Xinwei WANG

《机械工程前沿（英文）》 2009年 第4卷 第3期   页码 320-325 doi: 10.1007/s11465-009-0042-9

摘要： Within the framework of nonlinear electroelasticity, the anti-plane problem of a circular-arc interfacial crack between a circular piezoelectric inhomogeneity and an infinite piezoelectric matrix subjected to a far-field uniform loading is investigated by an electrical strip saturation model, the complex variable method, and the method of analytical continuation. Explicit closed form expressions for the complex potentials in both the matrix and the inclusion, and the stress intensity factor at the crack tip are presented. Comparison with some related solutions based on the linear electroelastic theory shows the validity of the present solutions

关键词： piezoelectric material     arc crack     strip saturation     stress intensity factor    

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CC@BCN@PANI core-shell nanoarrays as ultra-high cycle stability cathode for Zn-ion hybrid supercapacitors

《能源前沿（英文）》 2023年 第17卷 第4期   页码 555-566 doi: 10.1007/s11708-023-0882-8

摘要： Exploring cathode materials that combine excellent cycling stability and high energy density poses a challenge to aqueous Zn-ion hybrid supercapacitors (ZHSCs). Herein, polyaniline (PANI) coated boron-carbon-nitrogen (BCN) nanoarray on carbon cloth surface is prepared as advanced cathode materials via simple high-temperature calcination and electrochemical deposition methods. Because of the excellent specific capacity and conductivity of PANI, the CC@BCN@PANI core-shell nanoarrays cathode shows an excellent ion storage capability. Moreover, the 3D nanoarray structure can provide enough space for the volume expansion and contraction of PANI in the charging/discharging cycles, which effectively avoids the collapse of the microstructure and greatly improves the electrochemical stability of PANI. Therefore, the CC@BCN@PANI-based ZHSCs exhibit superior electrochemical performances showing a specific capacity of 145.8 mAh/g, a high energy density of 116.78 Wh/kg, an excellent power density of 12 kW/kg, and a capacity retention rate of 86.2% after 8000 charge/discharge cycles at a current density of 2 A/g. In addition, the flexible ZHSCs (FZHSCs) also show a capacity retention rate of 87.7% at the current density of 2 A/g after 450 cycles.

关键词： CC@BCN@PANI cathode     Zn-ion hybrid supercapacitor     core-shell nanoarrays     high energy density     ultra-high cycle stability    

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Development of a new wear resistant coating by arc spraying of a steel-based cored wire

Lidong ZHAO, Pia KUTSCHMANN, Binyou FU, Dingyong HE

《机械工程前沿（英文）》 2009年 第4卷 第1期   页码 1-4 doi: 10.1007/s11465-009-0012-2

摘要： In the present study, a cored wire of 304 L stainless steel as sheath material and NiB and WC-12Co as filler materials was designed and deposited to produce a new wear resistant coating containing amorphous phase by arc spraying. The microstructure of the coating was investigated. The porosity and hardness of the coating were determined. The wear performance of the coating was evaluated. The XRD and TEM analyses showed that there are high volume of amorphous phase and very fine crystalline grains in the coating. DTA measurements revealed that the crystallization of the amorphous phase occurred at 579.2°C. Because metallurgical processes for single droplets were non-homogenous during spraying, the lamellae in the coating have different hardness values, which lie between about 700 and 1250 HV . The abrasive wear test showed that the new Fe-based coating was very wear resistant.

关键词： amorphous phase     arc spraying     microstructure     wear     cored wire    

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Local arc discharge mechanism and requirements of power supply in micro-arc oxidation of magnesium alloy

Ming CHEN, Yuezhou MA, Yuan HAO,

《机械工程前沿（英文）》 2010年 第5卷 第1期   页码 98-105 doi: 10.1007/s11465-009-0088-8

摘要： To study the requirements of the power supply in micro-arc oxidation (MAO) of magnesium alloy, many experiments were performed under the DC, unipolar, and ambipolar pulse output modes. Based on the experimental results and electric arc theory, the separate local arc discharge mechanism was put forward. It is considered that magnesium MAO process consists of three stages including anodic oxidation, micro-arc oxidation, and large-arc discharge in turn with increasing source voltage. The MAO film is composed of metal oxides that resulted from numerous discrete local arc discharges, which accumulate the non-equilibrium structure after undergoing sudden heating and cooling cycles. Separate local arc discharge is caused by the process in which the oxygen-based gas is ionized in the conduct channel bearing electric field intensity, changed from insulator to conductor that presents sharp negative resistance effect, and produced partially high temperature to ignite locally metal oxidation. The local arc discharge model is described as four courses: gas created from electrolysis, arc discharge, metals oxidization, and cooling and shrinking of oxides. The purpose of pulse supply is to inhibit the large-arc discharge by intervening proper cooling time, which cannot be actualized by a unipolar pulse mode because of the strong capacitive load characteristics but can be reached by an ambipolar pulse supply because the negative pulse period acts as cooling time. Using a discharge loop to remove the influence of load capacitive, a new type of pulse power supply for MAO is developed, so that the large-arc problem is resolved effectively, the film-forming efficiency is improved, and the pollution of the film and electrolyte caused by negative voltage is avoided.

关键词： micro-arc oxidation     local arc discharge     pulse power supply     magnesium alloy    

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Three-dimensional finite difference analysis of shallow sprayed concrete tunnels crossing a reverse fault

Masoud RANJBARNIA, Milad ZAHERI, Daniel DIAS

《结构与土木工程前沿（英文）》 2020年 第14卷 第4期   页码 998-1011 doi: 10.1007/s11709-020-0621-8

摘要： Urban tunnels crossing faults are always at the risk of severe damages. In this paper, the effects of a reverse and a normal fault movement on a transversely crossing shallow shotcreted tunnel are investigated by 3D finite difference analysis. After verifying the accuracy of the numerical simulation predictions with the centrifuge physical model results, a parametric study is then conducted. That is, the effects of various parameters such as the sprayed concrete thickness, the geo-mechanical properties of soil, the tunnel depth, and the fault plane dip angle are studied on the displacements of the ground surface and the tunnel structure, and on the plastic strains of the soil mass around tunnel. The results of each case of reverse and normal faulting are independently discussed and then compared with each other. It is obtained that deeper tunnels show greater displacements for both types of faulting.

关键词： urban tunnel     sprayed concrete     reverse fault     normal fault     finite difference analysis    

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Submerged arc plasma system combined with ozone oxidation for the treatment of wastewater containing

《环境科学与工程前沿（英文）》 2021年 第15卷 第5期 doi: 10.1007/s11783-020-1384-0

摘要：

• Submerged arc plasma was introduced in terms of wastewater treatment.

关键词： Thermal plasma     Submerged arc plasma     Wastewater     Ozone     Phenol     Highly energetic electron    

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电沉积Zn-Fe-SiO2复合镀层研究

张英杰,范云鹰,董鹏,罗少林

《中国工程科学》 2008年 第10卷 第3期   页码 93-96

摘要：

报告了电沉积Zn-Fe-SiO2复合镀层的研究结果，论述了电流密度、极间距、搅拌方式、阳极数量及排布方式、添加剂等对Zn-Fe-SiO2复合镀层的影响及试验所取得的技术指标试验结果表明，Zn-Fe-SiO2复合镀层工艺具有过程稳定性好，维护措施简单方便，生产的环保及安全性好等优点。

关键词： 电沉积     复合镀层     Zn-Fe-SiO2    

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Durability of plasma-sprayed Cr3C2-NiCr coatings under rolling contact conditions

Xiancheng ZHANG, Fuzhen XUAN, Shantung TU, Binshi XU, Yixiong WU

《机械工程前沿（英文）》 2011年 第6卷 第1期   页码 118-135 doi: 10.1007/s11465-011-0127-0

摘要：

The aim of this paper was to address the rolling contact fatigue (RCF) failure mechanisms of plasma-sprayed Cr3C2-NiCr coatings under different tribological conditions of contact stress. Weibull distribution plots of fatigue lives of the coated specimens at different contact stresses were obtained. The failure modes of coatings were identified on the basis of wore surface observations of the failed coatings. Results showed that the RCF failure modes can be classified into four main categories, i.e., surface abrasion, spalling, cohesive delamination, and interfacial delamination. The probabilities of the surface abrasion and spalling type failures were relatively high at low contact stress. When the coatings were subjected to abrasion and spalling type failures, the failure of the coating was depended on the microstrcture of the coating. The stress concentration near the micro-defects in the coating may be the may reason for the formation of spall. The coatings were prone to fail in delamination under higher contact stresses. However, the delamination of coating may be related to distribution of shear stress amplitude within coating. The location of maximum shear stress amplitude can be used as a key parameter to predict the initiation of subsurface cracks within coating in rolling contact.

关键词： rolling contact fatigue     coating     Weibull distribution     failure mode     mechanism    

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g-CN-coated MnO hollow nanorod cathode for stable aqueous Zn-ion batteries

《化学科学与工程前沿（英文）》 2023年 第17卷 第2期   页码 217-225 doi: 10.1007/s11705-022-2214-7

摘要： Aqueous zinc-ion batteries are attracting considerable attention because of their high safety compared with conventional lithium-ion batteries. Manganese-based materials have been widely developed for zinc-ion batteries cathode owning to their low cost, high security and simple preparation. However, the severe volume expansion and poor stability during charging and discharging limit the further development of manganese-based cathodes. Herein, superior α-MnO2@g-C3N4 was successfully prepared for stable zinc-ion batteries (ZIBs) cathode by introducing g-C3N4 nanosheets. Compared with pure α-MnO2, α-MnO2@g-C3N4 has a specific capacity of 298 mAh·g–1 at 0.1 A·g–1. Even at 1 A·g–1, the α-MnO2@g-C3N4 still retains 100 mAh·g–1 (83.4% retention after 5000 cycles), implying its excellent cycling stability. The α-MnO2@g-C3N4-based cathode has the highest energy density (563 Wh·kg–1) and power energy density (2170 W·kg–1). This work provides new avenues for the development of a wider range of cathode materials for ZIBs.

关键词： α-MnO2 hollow nanorods     g-C3N4     heterojunction     aqueous Zn-ion batteries    

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ZN － 1阻尼橡胶材料的老化机理研究

张凯,马艳,谭云,梅军

《中国工程科学》 2009年 第11卷 第2期   页码 48-52

摘要：

采用加速老化试验方法对ZN－１阻尼橡胶材料的热氧老化性能进行了研究，获得了不同老化温度 及老化时间对硅橡胶泡沫材料力学性能及阻尼性能的影响规律研究结果表明，随着老化温度的升高及老 化时间的延长， ZN－１的拉伸强度出现了先下降后升高的现象，而扯断伸长率则表现为单调下降的趋势。同 时，还研究了ZN－１阻尼橡胶材料在热氧老化条件下微观结构与性能变化之间的关系，得到了ZN－ １阻尼橡 胶材料的热老化机理。

关键词： ZN-1阻尼橡胶材料     老化性能     微观结构     老化机理    

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Mathematical model and manufacture programming of loxodromic-type normal circular-arc spiral bevel gear

Zhenyun DUAN, Houjun CHEN, Zhilan JU, Jian LIU

《机械工程前沿（英文）》 2012年 第7卷 第3期   页码 312-321 doi: 10.1007/s11465-012-0308-5

摘要：

In this paper, loxodromic-type normal circular-arc spiral bevel gear is proposed as a novel application of the circular-arc tooth profile at the gear transmission with intersecting axes. Based on the principle of molding-surface conjugation, the study develops a mathematical model for the tooth alignment curve and the computational flow at the design stage to enable the generation of the tooth surface. Machining of the tooth surface is then carried out to determine the interference-free tool path of the numerical control (NC). Moreover, a pair of loxodromic-type normal circular-arc spiral bevel gears is manufactured on computer numerical control (CNC) machine tools. The proposed theory and method are experimentally investigated, and the obtained results primarily reflect the superior performance of the proposed novel gear.

关键词： loxodrome     circular-arc tooth profile     Wildhaber-Novikov (W-N) gear     spiral bevel gear    

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Accumulated damage process of thermal sprayed coating under rolling contact by acoustic emission technique

Jia XU,Zhen-yu ZHOU,Zhong-yu PIAO

《机械工程前沿（英文）》 2016年 第11卷 第3期   页码 227-232 doi: 10.1007/s11465-016-0395-9

摘要：

The accumulated damage process of rolling contact fatigue (RCF) of plasma-sprayed coatings was investigated. The influences of surface roughness, loading condition, and stress cycle frequency on the accumulated damage status of the coatings were discussed. A ball-on-disc machine was employed to conduct RCF experiments. Acoustic emission (AE) technique was introduced to monitor the RCF process of the coatings. AE signal characteristics were investigated to reveal the accumulated damage process. Result showed that the polished coating would resist the asperity contact and remit accumulated damage. The RCF lifetime would then extend. Heavy load would aggravate the accumulated damage status and induce surface fracture. Wear became the main failure mode that reduced the RCF lifetime. Frequent stress cycle would aggravate the accumulated damage status and induce interface fracture. Fatigue then became the main failure mode that also reduced the RCF lifetime.

关键词： accumulated damage     spray coating     rolling contact fatigue     acoustic emission    

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Relationship between heavy metal concentrations of herbaceous plants and soils at four Pb-Zn mining sites

Yuan LI , Yanqun ZU , Qixian FANG , Zhaohua GAO , Christian SCHVARTZ ,

《环境科学与工程前沿（英文）》 2009年 第3卷 第3期   页码 325-333 doi: 10.1007/s11783-009-0024-5

摘要： This paper studied the relationship between heavy metal concentrations of herbaceous plants and soils at four Pb-Zn mining sites in Yunnan, China. 50 herbaceous plant samples of 9 plant species from 4 families and 50 soil samples were collected and then ana1yzed for the tota1 concentrations of Pb, Cd, and Zn. The results showed that the average concentrations of Pb, Cd, and Zn in soil samples were 3772.83, 168.81, and 5385.65 mg/kg, respectively. The average concentrations of Pb, Cd, and Zn were 395.68, 28.14, and 1664.20 mg/kg in the shoots, and 924.12, 57.25 , and 1778.75 mg/kg in the roots, respectively. Heterospecific plants at the same site and conspecific plants at various sites had different average levels of Pb, Cd, and Zn, both in the shoots and the roots. Enrichment coefficients of Pb, Cd, and Zn were greater than 1 in 2, 3, and 9 herbaceous plant samples, respectively. Translocation factors of Pb, Cd, and Zn were greater than 1 in 10, 17, and 25 herbaceous plant samples, respectively. In all 50 samples, the concentrations of Pb, Cd, and Zn between the shoots and the roots, the shoots, and the soils, and the roots and the soils had significant positive relationships.

关键词： Pb     Cd     Zn     herbaceous plants     Pb-Zn mining areas     enrichment coefficient     translocation factor    

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Simultaneous removal of trihalomethanes by bimetallic Ag/Zn: kinetics study

Ahmed H A DABWAN, Satoshi KANECO, Hideyuki KATSUMATA, Kiyoyuki EGUSA, Tohru SUZUKI, Kiyohisa OHTA,

《化学科学与工程前沿（英文）》 2010年 第4卷 第3期   页码 322-327 doi: 10.1007/s11705-009-0261-y

摘要： In the present work, bimetallic silver/zinc was applied into the degradation of trihalomethanes, THMs: CHCl, CHBrCl, CHBrCl, and CHBr. The kinetics reaction rates and removal efficiencies of the THM compound mixtures, in the aqueous solutions, were investigated. Batch experiments were conducted under mild conditions, ambient temperature, and pressure. The primary degradation reaction followed a pseudo-first-order kinetic law. The first-order rate constants and the degradation efficiencies followed the decreasing order of CHBr>CHBrCl>CHBrCl>CHCl. The bond dissociation energy and hydrophilic/hydrophobic characteristics of the THM compounds may become the most important parameters affecting the degradation kinetics and efficiency by bimetallic Ag/Zn.

关键词： reaction     first-order     dissociation     degradation reaction     aqueous    

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标题 作者 时间 类型 操作

Experimental and modeling studies on installation of arc sprayed Zn anodes for protection of reinforced

Xianming SHI

期刊论文

Stress field near circular-arc interface crack tip based on electric saturation concept

Longchao DAI, Xinwei WANG

期刊论文

CC@BCN@PANI core-shell nanoarrays as ultra-high cycle stability cathode for Zn-ion hybrid supercapacitors

期刊论文

Development of a new wear resistant coating by arc spraying of a steel-based cored wire

Lidong ZHAO, Pia KUTSCHMANN, Binyou FU, Dingyong HE

期刊论文

Local arc discharge mechanism and requirements of power supply in micro-arc oxidation of magnesium alloy

Ming CHEN, Yuezhou MA, Yuan HAO,

期刊论文

Three-dimensional finite difference analysis of shallow sprayed concrete tunnels crossing a reverse fault

Masoud RANJBARNIA, Milad ZAHERI, Daniel DIAS

期刊论文

Submerged arc plasma system combined with ozone oxidation for the treatment of wastewater containing

期刊论文

电沉积Zn-Fe-SiO2复合镀层研究

张英杰,范云鹰,董鹏,罗少林

期刊论文

Durability of plasma-sprayed Cr3C2-NiCr coatings under rolling contact conditions

Xiancheng ZHANG, Fuzhen XUAN, Shantung TU, Binshi XU, Yixiong WU

期刊论文

g-CN-coated MnO hollow nanorod cathode for stable aqueous Zn-ion batteries

期刊论文

ZN － 1阻尼橡胶材料的老化机理研究

张凯,马艳,谭云,梅军

期刊论文

Mathematical model and manufacture programming of loxodromic-type normal circular-arc spiral bevel gear

Zhenyun DUAN, Houjun CHEN, Zhilan JU, Jian LIU

期刊论文

Accumulated damage process of thermal sprayed coating under rolling contact by acoustic emission technique

Jia XU,Zhen-yu ZHOU,Zhong-yu PIAO

期刊论文

Relationship between heavy metal concentrations of herbaceous plants and soils at four Pb-Zn mining sites

Yuan LI , Yanqun ZU , Qixian FANG , Zhaohua GAO , Christian SCHVARTZ ,

期刊论文

Simultaneous removal of trihalomethanes by bimetallic Ag/Zn: kinetics study

Ahmed H A DABWAN, Satoshi KANECO, Hideyuki KATSUMATA, Kiyoyuki EGUSA, Tohru SUZUKI, Kiyohisa OHTA,

期刊论文